| Data | In casa | Ospite | Risultato |
|---|---|---|---|
| 16/05/14 21.00 | FC Malaga | UD Levante | 1:0 |
| 17/05/14 16.00 | Real Madrid | Espanyol Barcellona | 3:1 |
| 17/05/14 18.00 | FC Barcellona | Atletico Madrid | 1:1 |
| 17/05/14 22.00 | FC Valencia | Celta Vigo | 2:1 |
| 18/05/14 12.00 | Real Sociedad | FC Villarreal | 1:2 |
| 18/05/14 18.00 | Real Valladolid | FC Granada | 0:1 |
| 18/05/14 18.00 | CA Osasuna | Real Betis Siviglia | 2:1 |
| 18/05/14 18.00 | UD Almeria | Athletic Bilbao | 0:0 |
| 18/05/14 18.00 | Rayo Vallecano | FC Getafe | 1:2 |
| 18/05/14 21.00 | FC Siviglia | FC Elche | 3:1 |