| Data | In casa | Ospite | Risultato |
|---|---|---|---|
| 19/07/20 17.00 | Deportivo Alaves | FC Barcellona | 0:5 |
| 19/07/20 18.30 | Real Valladolid | Real Betis Siviglia | 2:0 |
| 19/07/20 18.30 | FC Villarreal | SD Eibar | 4:0 |
| 19/07/20 21.00 | Espanyol Barcellona | Celta Vigo | 0:0 |
| 19/07/20 21.00 | FC Siviglia | FC Valencia | 1:0 |
| 19/07/20 21.00 | CD Leganes | Real Madrid | 2:2 |
| 19/07/20 21.00 | FC Granada | Athletic Bilbao | 4:0 |
| 19/07/20 21.00 | Atletico Madrid | Real Sociedad | 1:1 |
| 19/07/20 21.00 | CA Osasuna | RCD Mallorca | 2:2 |
| 19/07/20 21.00 | UD Levante | FC Getafe | 1:0 |