| Data | In casa | Ospite | Risultato |
|---|---|---|---|
| 12/05/12 20.00 | Real Sociedad | FC Valencia | 1:0 |
| 12/05/12 22.00 | Real Betis Siviglia | FC Barcellona | 2:2 |
| 13/05/12 20.00 | FC Villarreal | Atletico Madrid | 0:1 |
| 13/05/12 20.00 | FC Malaga | Sporting Gijon | 1:0 |
| 13/05/12 20.00 | Racing Santander | CA Osasuna | 2:4 |
| 13/05/12 20.00 | UD Levante | Athletic Bilbao | 3:0 |
| 13/05/12 20.00 | Real Madrid | RCD Mallorca | 4:1 |
| 13/05/12 20.00 | Espanyol Barcellona | FC Siviglia | 1:1 |
| 13/05/12 20.00 | Rayo Vallecano | FC Granada | 1:0 |
| 13/05/12 20.00 | FC Getafe | Real Saragossa | 0:2 |