| Data | In casa | Ospite | Risultato |
|---|---|---|---|
| 01/06/13 17.00 | Real Madrid | CA Osasuna | 4:2 |
| 01/06/13 19.00 | FC Barcellona | FC Malaga | 4:1 |
| 01/06/13 21.00 | UD Levante | Real Betis Siviglia | 1:1 |
| 01/06/13 21.00 | Deportivo La Coruna | Real Sociedad | 0:1 |
| 01/06/13 21.00 | Rayo Vallecano | Athletic Bilbao | 2:2 |
| 01/06/13 21.00 | RCD Mallorca | Real Valladolid | 4:2 |
| 01/06/13 21.00 | Celta Vigo | Espanyol Barcellona | 1:0 |
| 01/06/13 21.00 | Real Saragossa | Atletico Madrid | 1:3 |
| 01/06/13 21.00 | FC Granada | FC Getafe | 2:0 |
| 01/06/13 21.00 | FC Siviglia | FC Valencia | 4:3 |