| Data | In casa | Ospite | Risultato |
|---|---|---|---|
| 12/09/25 21.00 | FC Siviglia | FC Elche | 2:2 |
| 13/09/25 14.00 | FC Getafe | Real Oviedo | 2:0 |
| 13/09/25 16.15 | Real Sociedad | Real Madrid | 1:2 |
| 13/09/25 18.30 | Athletic Bilbao | Deportivo Alaves | 0:1 |
| 13/09/25 21.00 | Atletico Madrid | FC Villarreal | 2:0 |
| 14/09/25 14.00 | Celta Vigo | FC Girona | -:- |
| 14/09/25 16.15 | UD Levante | Real Betis Siviglia | -:- |
| 14/09/25 18.30 | CA Osasuna | Rayo Vallecano | -:- |
| 14/09/25 21.00 | FC Barcellona | FC Valencia | -:- |
| 15/09/25 21.00 | Espanyol Barcellona | RCD Mallorca | -:- |